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Beilstein J. Org. Chem. 2017, 13, 1524–1532, doi:10.3762/bjoc.13.152
Graphical Abstract
Scheme 1: Arylation of zinc meso-(bromophenyl)porphyrinates 1, 2 with benzothiazole and benzoxazole.
Scheme 2: Attempts of the arylation of zinc meso-(bromophenyl)porphyrinates 1 and 2 with benzoxazole and benz...
Scheme 3: Arylation of zinc meso-(bromophenyl)porphyrinates 1, 2 with benzothiazole, benzoxazole, N-methylben...
Scheme 4: Plausible action of palladium and copper catalysts with transmetalation step.
Scheme 5: Dirylation of zinc di-meso-(bromophenyl)porphyrinates 10–12 with benzothiazole, benzoxazole and N-m...
Scheme 6: Polyarylation of zinc tetrakis-meso-(bromophenyl)porphyrinate 18 with benzoxazole.
Beilstein J. Org. Chem. 2017, 13, 564–570, doi:10.3762/bjoc.13.55
Figure 1: A tripodal molecular pocket (a) [12] or jellyfish resembling receptors (b) [11,16].
Scheme 1: Example of Pd-catalyzed amination for modification of bile acid derivatives.
Scheme 2: Synthesis of 24-aminocholanols.
Scheme 3: Synthesis of 24-arylaminocholanols by Cu-catalyzed amination.
Scheme 4: Synthesis of 24-arylaminocholanols by Pd-catalyzed amination.
Figure 2: UV–vis spectra of 5c (50 μM solution in MeCN) before and after the addition of 5 equiv of metal per...
Beilstein J. Org. Chem. 2015, 11, 2297–2305, doi:10.3762/bjoc.11.250
Figure 1: Diamines and polyamines studied in Cu(I)-catalyzed amination reactions.
Scheme 1: N,N’-Diarylation of the diamines 1 and 2.
Scheme 2: Arylation of the diamines 1 and 2.
Scheme 3: Arylation of the diamines 3 and 4.
Scheme 4: Arylation of the diamines 1, 3, 4 with 2-fluoroiodobenzene.
Scheme 5: Arylation of the triamines 5 and 6.
Scheme 6: Arylation of the tetraamines 7 and 8.